47899-38-7

Basic information

• Product Name: trans-(triphenylphosphine)3PtCl⁽¹⁺⁾
• Synonyms: trans-(triphenylphosphine)3PtCl⁽¹⁺⁾
• CAS NO: 47899-38-7
• Molecular Weight: 1017.41
• Mol File: 47899-38-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-(triphenylphosphine)3PtCl⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: trans-(triphenylphosphine)3PtCl⁽¹⁺⁾(47899-38-7)
• EPA Substance Registry System: trans-(triphenylphosphine)3PtCl⁽¹⁺⁾(47899-38-7)

Safety Data

• Hazardous Substances Data: 47899-38-7(Hazardous Substances Data)

Upstream product

• 14264-16-5 bis(triphenylphosphine)nickel(II) chloride 
• 75-05-8 acetonitrile 
• 83719-67-9 [Pt₂Cl₂(SnCl₃)2(P(C₆H₅)3)2] 

Relevant articles and documents

Coordination chemistry of the metalloligand [Pt2(μ-S) 2(PPh3)4] with nickel(II) complexes - An electrospray mass spectrometry directed synthetic study

The reactivity of [Pt2(μ-S)2(PPh3) 4] towards a range of nickel(II) complexes has been probed using electrospray ionisation mass spectrometry coupled with synthesis and characterisation in selected systems. Reaction of [Pt2(μ-S) 2(PPh3)4] with [Ni(NCS)2(PPh 3)2] gives [Pt2(μ-S)2(PPh 3)4Ni(NCS)(PPh3)]+, isolated as its BPh4- salt; the same product is obtained in the reaction of [Pt2(μ-S)2(PPh3)4] with [NiBr2(PPh3)2] and KNCS. An X-ray structure determination reveals the expected sulfide-bridged structure, with an N-bonded thiocyanate ligand and a square-planar coordination geometry about nickel. A range of nickel(II) complexes NiL2, containing β-diketonate, 8-hydroxyquinolinate, or salicylaldehyde oximate ligands react similarly, giving [Pt2(μ-S)2(PPh3)4NiL] + cations.