479064-07-8Relevant academic research and scientific papers
Facile preparation and photophysics of near-infrared luminescent lanthanide(III) monoporphyrinate complexes
Foley, Timothy J.,Harrison, Benjamin S.,Knefely, Alison S.,Abboud, Khalil A.,Reynolds, John R.,Schanze, Kirk S.,Boncella, James M.
, p. 5023 - 5032 (2008/10/08)
The synthesis, characterization, and single crystal X-ray diffraction structures of a series of monoporphyrinate, trivalent lanthanide complexes with the monoanionic ligands hydridotris(1-pyrazolyl)borate (Tp) and (cyclopentadienyl)-tris(diethylphosphinito)cobaltate (L(OEt)) having the general formulas M(TPP)(L) (M = Yb, Tm, Er, Ho, Nd, Pr; TPP = 5,10,15,20-tetraphenylporphyrinate; L = Tp, L(OEt)) are described. The photophysical properties of these complexes are also presented including their absorption, emission, and transient absorption properties.
