480430-25-9Relevant academic research and scientific papers
Metal-acetylide addition to tetracyanoethylene
Reekie, Tristan A.,Gisselbrecht, Jean-Paul,Boudon, Corinne,Trapp, Nils,Diederich, Fran?ois
supporting information, p. 2414 - 2416 (2017/05/31)
Two push-pull chromophores that have shown utility in the field of molecular electronics and non-linear optics are DDMEBT (1, 2-(4-dimethylamino)phenyl)-3-((4-(dimethylamino)phenyl)ethynyl)buta-1,3-diene-1,1,4,4-tetracarbonitrile) and TDMEE (2, 4-(4-dimet
Donor-substituted cyanoethynylethenes: π-conjugation and band-gap tuning in strong charge-transfer chromophores
Moonen, Nicolle N. P.,Pomerantz, William C.,Gist, Robin,Boudon, Corinne,Gisselbrecht, Jean-Paul,Kawai, Tsuyoshi,Kishioka, Atsushi,Gross, Maurice,Irie, Masahiro,Diederich, Francois
, p. 3325 - 3341 (2007/10/03)
An extensive series of silyl-protected cyanoethynylethenes (CEEs) and N,N-dimethylanilino donor-substituted CEEs have been synthesized. More extended chromophores were constructed by selective silyl deprotection and subsequent oxidative acetylenic couplin
Cyanoethynylethenes: A class of powerful electron acceptors for molecular scaffolding
Moonen, Nicolle N. P.,Boudon, Corinne,Gisselbrecht, Jean-Paul,Seiler, Paul,Gross, Maurice,Diederich, Francois
, p. 3044 - 3047 (2007/10/03)
Extended π-electron acceptors, such as 1, have been constructed by the acetylenic scaffolding of a series of novel cyanoethynylethenes. Electrochemical analysis shows that acceptor strength is a function of πelectron conjugation length, and that a linear correlation exists between the electron affinities (B3LYP, 3-21G) and their first reduction potential.
