4808-49-5Relevant academic research and scientific papers
Photoinduced Electron Transfer (PET)-Mediated Fragmentation of Picolinium-Derived Redox Probes
Dunkel, Petra,Barosi, Anna,Dhimane, Hamid,Maurel, Fran?ois,Dalko, Peter I.
, p. 12920 - 12931 (2018)
The photolysis of covalently linked N-alkyl picolinium phenylacetate—carbazole dyads was analyzed experimentally and by using density functional theory (DFT) and time dependent-DFT (TD-DFT) calculations. In contrast to earlier observations efficient one and two-photon fragmentations conditions were found for 15 c (δu=0.16 GM at 730 nm) opening the way for the design of a novel class of “caged” compounds.
