481-28-7

Basic information

• Product Name: (S)-3-Hydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-one
• CAS NO: 481-28-7
• Molecular Weight: 290.446
• Mol File: 481-28-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (S)-3-Hydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-Hydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-one(481-28-7)
• EPA Substance Registry System: (S)-3-Hydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-one(481-28-7)

Safety Data

• Hazardous Substances Data: 481-28-7(Hazardous Substances Data)

Upstream product

• 19325-01-0 C₂₁H₃₄OS₂ 
• 571-20-0 (5α)-androstane-3β,17β-diol 
• 57711-44-1 Androsterone-dimethyl-tert.-butylsilyl-ether 
• 1192475-82-3 androstendione 
• 571-20-0 (3S,5S,10S,13S)-10,13-Dimethyl-hexadecahydro-cyclopenta[a]phenanthrene-3,17-diol 

Downstream Products

• 846-46-8 androstanedione 
• 571-20-0 (5α)-androstane-3β,17β-diol 
• 10481-80-8 13α-androsterone hydrazone 
• 2061-71-4 3α-hydroxy-17a-oxa-D-homo-5α-androstan-17-one 

Relevant articles and documents

Catalytic removal of tert-butyldimethylsilyl (TBS) ether by PVP-I

A mild, efficient and rapid protocol the deprotection of alcoholic TBDMS ethers using PVP-1 as catalyst in methanol, the procedure of deprotection of various TBDMS ethers were found to be very convenient, easy work-up, high yielding.

Heterogeneous Catalysis in Carbonyl Regeneration from 1,3-Dithiolanes and 1,3-Dithianes by Zirconium Sulfophenyl Phosphonate

Layered zirconium sulfophenyl phosphonate was found to be an efficient heterogeneous catalyst for mild hydrolysis of 1,2 dithiolanes and 1,3 dithianes to their corresponding carbonyl compounds.

CHEMOSELECTIVITY IN MOLYBDENUM CATALYZED ALCOHOL AND ALDEHYDE OXIDATIONS

Hydrogen peroxide in the presence of (NH4)6Mo7O24*4H2O and potassium carbonate is a chemoselective method to oxidize secondary alcohols to ketones and to oxidize aldehydes to acids, the latter also accelerated by cerium chloride.