4822-40-6Relevant academic research and scientific papers
1,6-Stannatropic strategy: Effective generation and cyclization of 1,5-dipoles from o-stannylmethylated thioanilides or phenyl isothiocyanates
Minakata, Satoshi,Kasano, Yukihiro,Ota, Hirofumi,Oderaotoshi, Yoji,Komatsu, Mitsuo
, p. 3693 - 3695 (2006)
A new method for the generation of 1,5-dipoles from o-stannylmethylated thioanilides via 1,6-stannatropy under neutral conditions was developed. Cyclization of the 1,5-dipoles afforded indole derivatives effectively. The strategy has potential for application to the generation of alternative 1,5-dipoles from o-stannylmethylated aryl isothiocyanates leading to indole derivatives having a stannylthio group that was readily converted to other functional groups.
