482288-71-1

Basic information

• Product Name: [(2-trimethylstannyl)phenyl] diethylphosphate
• CAS NO: 482288-71-1
• Molecular Weight: 393.007
• Mol File: 482288-71-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(2-trimethylstannyl)phenyl] diethylphosphate(CAS DataBase Reference)
• NIST Chemistry Reference: [(2-trimethylstannyl)phenyl] diethylphosphate(482288-71-1)
• EPA Substance Registry System: [(2-trimethylstannyl)phenyl] diethylphosphate(482288-71-1)

Safety Data

• Hazardous Substances Data: 482288-71-1(Hazardous Substances Data)

Upstream product

• 16462-86-5 2-(chlorophenyl) diethylphosphate 
• 16643-09-7 trimethylstannyl sodium 
• 37521-98-5 Tetraethyl 1,2-phenylene bis(phosphate) 

Relevant articles and documents

Synthesis of bis(trimethylstannyl)aryl compounds via an SRN1 mechanism with intermediacy of monosubstitution products

1,2-Bis(trimethylstannyl)benzene (1) and 2,2′-bis(trimethylstannyl)-1,1′-binaphthyl (2), useful as intermediates in the preparation of bidentate Lewis acids, have been synthesized from simple phenols through a two-step sequence. Thus, 2-chlorophenol, 1,2-dihydroxybenzene, and binaphthol were converted into the corresponding aryl diethyl phosphate esters 4-6, which on reaction with sodium trimethylstannide (3) in liquid ammonia, under irradiation, afforded 1 and 2, respectively, in good yields (66-82%). The results obtained clearly indicate that the reactions proceed through an SRN1 mechanism and involve the intermediacy of a monosubstitution product.