482621-05-6Relevant articles and documents
Convergent synthesis of antiparallel cyclobolaphiles having two diacetylenes: Mimetics of membrane components that are found in archaea
Miyawaki, Kazuhiro,Goto, Rie,Takagi, Toshiyuki,Shibakami, Motonari
, p. 1467 - 1470 (2007/10/03)
Chiral 48-membered antiparallel cyclobolaphiles and their diastereomer having two diacetylenes were convergently synthesized utilizing both cross-coupling method (Cul, pyrrolidine) and Glaser intramolecular cyclization, starting from commercially available D- and L-1, 2-O-isopropylidene-sn-glycerol as chiral sources.