484647-42-9

Basic information

• Product Name: 2-acetyl-3,4-di-O-benzyl-6-O-t-butyldimethylsilyl-D-mannopyranozyl trichloroacetimidate
• Synonyms: 2-acetyl-3,4-di-O-benzyl-6-O-t-butyldimethylsilyl-D-mannopyranozyl trichloroacetimidate
• CAS NO: 484647-42-9
• Molecular Weight: 661.095
• Mol File: 484647-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-acetyl-3,4-di-O-benzyl-6-O-t-butyldimethylsilyl-D-mannopyranozyl trichloroacetimidate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetyl-3,4-di-O-benzyl-6-O-t-butyldimethylsilyl-D-mannopyranozyl trichloroacetimidate(484647-42-9)
• EPA Substance Registry System: 2-acetyl-3,4-di-O-benzyl-6-O-t-butyldimethylsilyl-D-mannopyranozyl trichloroacetimidate(484647-42-9)

Safety Data

• Hazardous Substances Data: 484647-42-9(Hazardous Substances Data)

Upstream product

• 29073-91-4 1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-D-mannopyranosyl bromide 
• 3254-16-8 3,4,6-tri-O-acetyl-1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 
• 83-87-4 D-Mannose pentaacetate 

Downstream Products

• 484647-54-3 benzyl 2-(2-acetyl-3,4-di-O-benzyl-6-O-t-butyldimethylsilyl-α-D-mannopyranosyl)-3,4,7-tri-O-benzyl-6-deoxy-6-(N-methyl-benzyloxycarbonylamino)-L-glycero-α-D-gluco-heptopyranoside 

Relevant articles and documents

Total synthesis of desferrisalmycin B

The first total synthesis of a naturally occurring siderophore antibiotic, desferrisalmycin B, is described, and the configuration of the unknown stereocenter is assigned. The synthesis features a synthetic strategy of constructing the novel amino-heptopyranoside component by stereoselective dihydroxylation followed by a Bose-modified Mitsunobu reaction. Through this convergent approach, other members of salmycins should also be synthetically accessible.