485805-43-4

Basic information

• Product Name: Benzene, 1-methoxy-3-[(1E)-2-(2,6,6-trimethyl-2-cyclohexen-1-yl)ethenyl]-
• CAS NO: 485805-43-4
• Molecular Formula: C18H24O
• Molecular Weight: 256.388
• Mol File: 485805-43-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-3-[(1E)-2-(2,6,6-trimethyl-2-cyclohexen-1-yl)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-3-[(1E)-2-(2,6,6-trimethyl-2-cyclohexen-1-yl)ethenyl]-(485805-43-4)
• EPA Substance Registry System: Benzene, 1-methoxy-3-[(1E)-2-(2,6,6-trimethyl-2-cyclohexen-1-yl)ethenyl]-(485805-43-4)

Safety Data

• Hazardous Substances Data: 485805-43-4(Hazardous Substances Data)

Upstream product

• 14505-74-9 α-cyclocitral 
• 18880-05-2 3-methoxybenzyl-triphenylphosphonium chloride 
• 6971-51-3 3-methoxybenzyl alcohol 
• 824-98-6 m-methoxybenzyl chloride 

Downstream Products

• 485805-44-5 3-(3-methoxyphenethyl)-2,4,4-trimethyl-1-cyclohexene 

Relevant articles and documents

First total synthesis of an analogue of montbretyl 12-methyl ether

The first total synthesis of the title compound 1 was accomplished starting from α-cyclocitral and benzyl triphenylphosphonium chloride 3 in seven steps via a strategy of AC→ABC. In the synthesis, t-BuOK/t-BuOH system was utilised for enolisation and the iso-propyl group was introduced in the last step.