4861-14-7Relevant academic research and scientific papers
Alkoxysilylamine compounds and applications thereof
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Page/Page column, (2014/07/07)
Described herein are alkoxysilylamine precursors having the following Formulae A and B: wherein R1 and R4 are independently selected from a linear or branched C1 to C10 alkyl group, a C3 to C12 alkenyl group, a C3 to C12 alkynyl group, a C4 to C10 cyclic alkyl group, and a C6 to C10 aryl group and wherein R2, R3, R4, R5, and R6 are independently selected from the group consisting of hydrogen, a linear or branched C1 to C10 alkyl group, a C2 to C12 alkenyl group, a C2 to C12 alkynyl group, a C4 to C10 cyclic alkyl, a C6 to C10 aryl group, and a linear or branched C1 to C10 alkoxy group. Also described herein are deposition processes using at least one precursor have Formulae A and/or B described herein.
Nonhydrolytic synthesis of branched alkoxysiloxane oligomers Si[OSiH(OR)2]4 (R = Me, Et)
Wakabayashi, Ryutaro,Kawahara, Kazufumi,Kuroda, Kazuyuki
supporting information; experimental part, p. 5273 - 5277 (2010/10/21)
Beyond silanol: A branched siloxane oligomer bearing terminal dialkoxysilyl groups was nonhydrolytically synthesized by direct alkoxysilylation of a tetraalkoxysilane with a chlorodialkoxysilane in the presence of the Lewis acid BiCl3 (see scheme). The reaction proceeds without the formation of intermediate silanol groups, and provides a selective route for siloxane-based oligomers. (Chemical equation presented)
