486429-69-0Relevant academic research and scientific papers
Phosphinoselenothioic acids and their salts: Synthesis, characterization, and reaction with electrophiles
Kimura, Tsutomu,Murai, Toshiaki,Miwa, Akihiro,Kurachi, Daisuke,Yoshikawa, Haruhisa,Kato, Shinzi
, p. 5611 - 5617 (2007/10/03)
Phosphinoselenothioic acid ammonium salts were synthesized in good yields by reacting phosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] esters with ammonium fluorides. Phosphinoselenothioic acid alkali metal salts were obtained as 18-crown-6 ether co
Selenothiophosphinic acid salts: Efficient synthesis, structure and reactivity
Murai, Toshiaki,Kimura, Tsutomu,Miwa, Akihiro,Kurachi, Daisuke,Kato, Shinzi
, p. 914 - 915 (2007/10/03)
An efficient synthesis of selenothiophosphinic acid salts is achieved by reacting selenothiophosphinic acid S-(2-trimethylsilyl)ethyl esters with ammonium or alkali metal fluorides. The X-ray structure analysis of the potassium 18-crown-6 selenothiophosphinic acid salt shows that the salt is monomeric. Alkylation of the salts proceeds at the selenium atom whereas acylation occurs at the sulfur atom.
