486429-70-3

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 29949-69-7 tert-butylchlorophenylphosphane 
• 754-05-2 ethenyltrimethylsilane 
• 861150-48-3 phosphorodithioic acid O,O-diethyl ester S-[(2-trimethylsilyl)ethyl] ester 
• 18143-30-1 2-trimethylsilylethanethiol 
• 146880-01-5 P-(1,1-dimethylethyl)-P-phenylphosphinoselenoic chloride 

Downstream Products

• 486429-74-7 P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid Se-methyl ester 

Relevant academic research and scientific papers

P-chiral phosphinoselenoic chlorides and phosphinochalcogenoselenoic acid esters: Synthesis, characterisation, and conformational studies

(Chemical Equation Presented) P-Chiral alkyl or aryl phenylphosphinoselenoic chlorides were obtained by reacting PhPCl2 with Grignard reagents and elemental selenium. P-Chiral dialkyl chlorides were also obtained by treating PCl3 with two different Grignard reagents and elemental selenium. The structure of the chloride was determined by X-ray molecular structure analysis. P-Chiral phosphinochalcogenoselenoic acid esters bearing a P=Se double bond were synthesized by treating the chlorides with alkali metal alkoxide and chalcogenolates, whereas those bearing a P-Se single bond were obtained by sequential treatment of the chlorides with sodium hydroxide, sulfide or selenide, and alkyl iodides. X-ray molecular structure analyses of esters showed that they adopted gauche conformations. The computational results supported the observed conformational preference. Natural bond orbital analyses of the model compounds showed that two types of nonbonding orbital interactions, nE′ → σ*P=E and nE → σ*P-E′, are important in these compounds. Linear correlations were observed between the experimental 77Se NMR chemical shifts or the coupling constants of P-Se bonds in the esters and the calculated P-Se bond lengths of the model compounds.

Phosphinoselenothioic acids and their salts: Synthesis, characterization, and reaction with electrophiles

Phosphinoselenothioic acid ammonium salts were synthesized in good yields by reacting phosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] esters with ammonium fluorides. Phosphinoselenothioic acid alkali metal salts were obtained as 18-crown-6 ether co

Selenothiophosphinic acid salts: Efficient synthesis, structure and reactivity

An efficient synthesis of selenothiophosphinic acid salts is achieved by reacting selenothiophosphinic acid S-(2-trimethylsilyl)ethyl esters with ammonium or alkali metal fluorides. The X-ray structure analysis of the potassium 18-crown-6 selenothiophosphinic acid salt shows that the salt is monomeric. Alkylation of the salts proceeds at the selenium atom whereas acylation occurs at the sulfur atom.