4866-62-0Relevant articles and documents
X-Ray Analysis of 6-Ethoxycarbonyl-4-ethylpyrazolopyrimidin-7(4H)-one and 6-Ethoxycarbonyl-4-ethyl-1,2,4-triazolopyrimidin-7(4H)-one
Clayton, J. Peter,Rogers, Norman H.,Smith, Victoria J.,Stevenson, Robert,King, Trevor J.
, p. 1347 - 1351 (2007/10/02)
The product obtained by treating 6-ethoxycarbonyl-7-hydroxypyrazolopyrimidine (2a) with ethyl iodide is shown by X-ray analysis to be 6-ethoxycarbonyl-4-ethylpyrazolopyrimidin-7(4H)-one (3a).When 3-amino-1,2,4-triazole (5a) was cyclised with diethyl ethoxymethylenemalonate the product was shown to have the structure (2b), rather than (6), by an X-ray analysis of its N-ethyl derivative, 6-ethoxycarbonyl-4-ethyl-1,2,4-triazolopyrimidin-7(4H)-one (3d).Carbon-13 chemical shift values in the above and related compounds have been assigned.