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Benzenamine, 2,3-dimethyl-N-phenyl-, also known as 2,3-dimethyl-N-phenylaniline or 2,3-dimethyl-N-phenylbenzenamine, is an organic compound with the chemical formula C14H15N. It is a derivative of aniline, where two methyl groups are attached to the benzene ring at the 2nd and 3rd positions, and a phenyl group is attached to the nitrogen atom. Benzenamine, 2,3-dimethyl-N-phenyl- is a colorless to pale yellow solid with a melting point of 41-43°C and a boiling point of 320-322°C. It is soluble in organic solvents such as ethanol, acetone, and benzene, but insoluble in water. Benzenamine, 2,3-dimethyl-N-phenyl-, has various applications in the chemical industry, including the synthesis of dyes, pharmaceuticals, and agrochemicals. It is also used as an intermediate in the production of certain polymers and as a reagent in analytical chemistry. Due to its potential health hazards, it is important to handle Benzenamine, 2,3-dimethyl-N-phenyl- with care and follow proper safety procedures.

4869-11-8

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4869-11-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 4869-11-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,8,6 and 9 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 4869-11:
(6*4)+(5*8)+(4*6)+(3*9)+(2*1)+(1*1)=118
118 % 10 = 8
So 4869-11-8 is a valid CAS Registry Number.

4869-11-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name N-phenyl-2,3-dimethylphenylamine

1.2 Other means of identification

Product number -
Other names (2,3-dimethyl-phenyl)-phenyl-amine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4869-11-8 SDS

4869-11-8Relevant academic research and scientific papers

NOVEL CATALYSTS

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Page/Page column 66, (2012/06/01)

The present invention provides novel compounds and ligands that are useful in transition metal catalyzed cross-coupling reactions. For example, the compounds and ligands of the present invention are useful in palladium or gold catalyzed cross-coupling reactions.

A highly versatile catalyst system for the cross-coupling of aryl chlorides and Amines

Lundgren, Rylan J.,Sappong-Kumankumah, Antonia,Stradiotto, Mark

supporting information; experimental part, p. 1983 - 1991 (2010/07/03)

The syntheses of 2-(di-tertbutylphosphino)-N,N-dimethylaniline (L1, 71%) and 2-(di-1-adamantylphosphino)-N,N-dimethylaniline (L2, 74%), and their application in BuchwaldHartwig amination, are reported. In combination with [Pd(allyl)Cl]2 or [Pd(cinnamyl)Cl]2, these structurally simple and air-stable P,N ligands enable the cross-coupling of aryl and heteroaryl chlorides, including those bearing as substituents enolizable ketones, ethers, esters, carboxylic acids, phenols, alcohols, olefins, amides, and halogens, to a diverse range of amine and related substrates that includes primary alkyl- and arylamines, cyclic and acyclic secondary amines, N-H imines, hydrazones, lithium amide, and ammonia. In many cases, the reactions can be performed at low catalyst loadings (0.5-0.02 mol % Pd) with excellent functional group tolerance and chemoselectivity. Examples of cross-coupling reactions involving 1,4-bromochlorobenzene and iodobenzene are also reported. Under similar conditions, inferior catalytic performance was achieved when using Pd(OAc)2, PdCl2, [PdCl2(cod)] (cod = 1,5-cyclooctadiene), [PdCl 2(MeCN)2], or [Pd2(dba)3] (dba = dibenzylideneacetone) in combination with L1 or L2, or by use of [Pd(allyl)Cl]2 or [Pd(cinnamyl)Cl]2 with variants of L1 and L2 bearing less basic or less sterically demanding substituents on phosphorus or lacking an ortto-dimethylamino fragment. Given current limitations associated with established ligand classes with regard to maintaining high activity across the diverse possible range of C-N coupling applications, L1 and L2 represent unusually versatile ligand systems for the cross-coupling of aryl chlorides and amines

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