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(1S,3aα,8aα,9S)-Decahydro-4,8,8-trimethyl-1β,4β-methanoazulene-9-carboxylic acid is a complex organic compound with a molecular formula of C15H23O2. It is a derivative of the azulenecarboxylic acid family, characterized by its decahydro structure, which means it contains ten hydrogen atoms in a cyclic structure. The compound features a unique arrangement of methyl groups at positions 4, 8, and 8a, and a carboxylic acid functional group at the 9-position. This specific stereochemistry, indicated by the prefixes (1S,3aα,8aα,9S), describes the three-dimensional arrangement of the molecule's atoms. The compound is of interest in organic chemistry and may have potential applications in the synthesis of various pharmaceuticals and other chemical products due to its unique structure and properties.

487-74-1

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487-74-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 487-74-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,8 and 7 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 487-74:
(5*4)+(4*8)+(3*7)+(2*7)+(1*4)=91
91 % 10 = 1
So 487-74-1 is a valid CAS Registry Number.

487-74-1Relevant academic research and scientific papers

Cobalt catalyzed oxidation of cyclic alkenes with molecular oxygen: Allylic oxidation versus double bond attack

Madhava Reddy,Punniyamurthy,Iqbal, Javed

, p. 159 - 162 (2007/10/02)

Cobalt (II) Schiff's base complex 1 and 2 exhibit a remarkable chemoselectivity during oxidation of cyclic alkenes with molecular oxygen in the presence of 2-methylpropanal. Catalyst 1 encourages the oxidation of double bond to give epoxide as the major product whereas catalyst 2 promotes mainly the allylic oxidation leading to allylic alcohols or enones.

Longifolene as a chiron: Extraction of the bicyclic core of the spongian-type diterpenoids

Mehta,Thomas

, p. 1831 - 1838 (2007/10/02)

A short degradation of (+)-longifolene 1 to hydroazulene (+)-9 is described. Restructuring of 1 to a novel tricyclic framework (-)-10 is also reported.

A Convenient One-pot Hydroboration / Isomerization / Oxidation of Longifolene to Isolongifolol

Vyas, Pramod,Nayak, U. R.

, p. 337 - 339 (2007/10/02)

A convenient one-pot hydroboration / isomerization / oxidation of longifolene (1) to the thermodynamically more stable epimer, isolongifolol (3) is described.Furthermore, a practical in situ method for the hydroboration of 1 in THF, has been optimised to generate the less stable epimer, longifolol (2).

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