488090-77-3Relevant articles and documents
On the mechanism of the reaction of organic azides with transition metals: Evidence for triplet nitrene capture
Abu-Omar, Mahdi M.,Shields, Catherine E.,Edwards, Nicola Y.,Eikey, Rebecca A.
, p. 6203 - 6207 (2005)
(Chemical Equation Presented) High-valent imido complexes are obtained by reaction of the manganese-(III) corrole [Mn(tpfc)] with aryl azides by a novel reaction mechanism in which singlet nitrene undergoes intersystem crossing to the triplet state, which