488090-77-3Relevant academic research and scientific papers
On the mechanism of the reaction of organic azides with transition metals: Evidence for triplet nitrene capture
Abu-Omar, Mahdi M.,Shields, Catherine E.,Edwards, Nicola Y.,Eikey, Rebecca A.
, p. 6203 - 6207 (2005)
(Chemical Equation Presented) High-valent imido complexes are obtained by reaction of the manganese-(III) corrole [Mn(tpfc)] with aryl azides by a novel reaction mechanism in which singlet nitrene undergoes intersystem crossing to the triplet state, which
The elusive terminal imido of manganese(v)
Eikey, Rebecca A.,Khan, Saeed I.,Abu-Omar, Mahdi M.
, p. 3592 - 3595 (2007/10/03)
At last, terminal imido complexes of manganese(V), the postulated intermediates in aziridination and amination reactions, have been prepared. The structurally well-defined (imido)manganese(V) corroles, 2 and 3, are easily synthesized from manganese(III) c
