4910-26-3Relevant articles and documents
Metal-Free Catalytic Synthesis of Thiocarbamates Using Sodium Sulfinates as the Sulfur Source
Bao, Pengli,Wang, Leilei,Yue, Huilan,Shao, Yun,Wen, Jiangwei,Yang, Daoshan,Zhao, Xiaohui,Wang, Hua,Wei, Wei
, p. 2976 - 2983 (2019)
A novel molecular iodine-catalyzed protocol for the construction of thiocarbamates from readily available sodium sulfinates, isocyanides, and water has been described. The present methodology offers a facile and practical route to a variety of thiocarbamates in moderate to good yields with favorable functional group tolerance by use odorless sodium sulfinates as the sulfur source. The mechanistic studies suggest the present transformation involves a radical process.
Clean preparation of S-thiocarbamates with in situ generated hydroxide in 2-methyltetrahydrofuran
Bao, Wen-Hu,Wang, Zheng,Tang, Xiao,Zhang, Yun-Fu,Tan, Jia-Xi,Zhu, Qin,Cao, Zhong,Lin, Ying-Wu,He, Wei-Min
, p. 2259 - 2262 (2019)
A simple and clean protocol for the synthesis of various alkyl and (hetero)aryl S-thiocarbamates was established. The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a
Iodine-Catalyzed Odorless Synthesis of S-Thiocarbamates with Sulfonyl Chlorides as a Sulfur Source
Bao, Wen-Hu,He, Min,Wang, Jing-Ting,Peng, Xin,Sung, Men,Tang, Zilong,Jiang, Si,Cao, Zhong,He, Wei-Min
, p. 6065 - 6071 (2019/05/24)
A general and efficient protocol for the direct preparation of various S-thiocarbamates with readily available and inexpensive sulfonyl chlorides as an odorless sulfur source was developed. The employment of easily available reactants, excellent functiona