492455-07-9Relevant academic research and scientific papers
One pot/two donors/one diol give one differentiated trisaccharide: Powerful evidence for reciprocal donor-acceptor selectivity (RDAS)
Fraser-Reid, Bert,Lopez, J. Cristobal,Radhakrishnan,Nandakumar,Gomez, Ana M.,Uriel, Clara
, p. 2104 - 2105 (2002)
Three component, one-pot reactions involving equimolar amounts of the acceptor diol and both armed and disarmed donors presented simultaneously, produce a single double-differential glycosidation product; this phenomenon provides evidence for Reciprocal D
A study of n-pentenylorthoesters having manno, gluco and galacto configurations in regioselective glycosylations
Jayaprakash,Fraser-Reid, Bert
, p. 490 - 498 (2008/03/13)
Kochetkov's extensive investigations of glycosyl orthoester and their analogs as glycosyl donors revealed that the alkyl derivatives were plagued by competition between the departing alcohol and the incoming acceptor. n-Pentenyl orthoesters (NPOEs) obviat
Regioselective strategies mediated by lanthanide triflates for efficient assembly of oligomannans
Jayaprakash,Chaudhuri, Siddhartha Ray,Murty, Changalvala V. S. R.,Fraser-Reid, Bert
, p. 5534 - 5545 (2008/02/08)
(Chemical Equation Presented) Readily prepared mannosyl n-pentenylorthoesters (NPOEs) serve as donors in themselves and as convenient intermediates for other glycosyl donors, such as n-pentenyl glycosides (NPGs), thioglycosides, and trichloroacetimidates.
