117841-64-2Relevant academic research and scientific papers
Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(III) triflate
Xolin, Amandine,Losa, Romain,Kaid, Aicha,Tresse, Cédric,Beau, Jean-Marie,Boyer, Fran?ois-Didier,Norsikian, Stéphanie
, p. 325 - 335 (2018/01/12)
The activation of aryl glycosyl sulfone donors has been achieved using scandium(iii) triflate and has led to the selective preparation of α-mannosides resulting from a post-glycosylation anomerization.
Methyl glycosides are identified as glycosyl donors for the synthesis of glycosides, disaccharides and oligosaccharides
Vidadala, Srinivasa Rao,Hotha, Srinivas
supporting information; scheme or table, p. 2505 - 2507 (2009/09/30)
Stable methyl glycosides are identified as glycosyl donors in the presence of AuBr3 in acetonitrile; a panel of aglycones comprising aliphatic, alicyclic, steroidal and sugar alcohols are examined successfully for the glycosylation reaction and
Synthesis of a key Mycobacterium tuberculosis biosynthetic phosphoinositide intermediate
Jayaprakash,Lu, Jun,Fraser-Reid, Bert
, p. 3815 - 3819 (2007/10/03)
Regioselective mannosylations of a myoinositol acceptor diol are readily achieved by Lewis acid mediated iodinolysis of n-pentenyl ortho-esters. The procedure affords a psuedotrisaccharide to which the phosphoglyceryl and other lipid residues are added le
One-pot chemo-, regio-, and stereoselective double-differential glycosidation mediated by lanthanide triflates
Jayaprakash,Fraser-Reid, Bert
, p. 4211 - 4214 (2007/10/03)
(Chemical Equation Presented) Nuanced activation of n-pentenyl, thioglycoside, and trichloroacetimidate donors by lanthanide salts coupled with donor/acceptor matching can simplify oligosaccharide assembly. Thus, a one-pot, double-differential glycosidati
Studies related to synthesis of glycophosphatidylinositol membrane-bound protein anchors. 5. n-pentenyl ortho esters for mannan components
Roberts, Carmichael,Madsen, Robert,Fraser-Reid, Bert
, p. 1546 - 1553 (2007/10/02)
Procedures for rapid assembly of multigram amounts of mannan components have been examined. Although these studies are reported in the context of the mannan moiety of the glycan anchors of membrane-bound glycoproteins, the procedures should be applicable
