117841-64-2Relevant articles and documents
Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(III) triflate
Xolin, Amandine,Losa, Romain,Kaid, Aicha,Tresse, Cédric,Beau, Jean-Marie,Boyer, Fran?ois-Didier,Norsikian, Stéphanie
, p. 325 - 335 (2018/01/12)
The activation of aryl glycosyl sulfone donors has been achieved using scandium(iii) triflate and has led to the selective preparation of α-mannosides resulting from a post-glycosylation anomerization.
Synthesis of a key Mycobacterium tuberculosis biosynthetic phosphoinositide intermediate
Jayaprakash,Lu, Jun,Fraser-Reid, Bert
, p. 3815 - 3819 (2007/10/03)
Regioselective mannosylations of a myoinositol acceptor diol are readily achieved by Lewis acid mediated iodinolysis of n-pentenyl ortho-esters. The procedure affords a psuedotrisaccharide to which the phosphoglyceryl and other lipid residues are added le
Studies related to synthesis of glycophosphatidylinositol membrane-bound protein anchors. 5. n-pentenyl ortho esters for mannan components
Roberts, Carmichael,Madsen, Robert,Fraser-Reid, Bert
, p. 1546 - 1553 (2007/10/02)
Procedures for rapid assembly of multigram amounts of mannan components have been examined. Although these studies are reported in the context of the mannan moiety of the glycan anchors of membrane-bound glycoproteins, the procedures should be applicable