493021-43-5Relevant articles and documents
DMSO as a Methine Source in TFA-Mediated One-Pot Tandem Regioselective Synthesis of 3-Substituted-1-Aryl-1 H-Pyrazolo-[3,4- b]quinolines from Anilines and Pyrazolones
Yadav, Pushpendra,Awasthi, Annapurna,Gokulnath, Sabapathi,Tiwari, Dharmendra Kumar
, p. 2658 - 2666 (2021/02/01)
An acid-mediated and DMSO participant one-pot tandem synthesis of 3-substituted-1-aryl-1H-pyrazolo-[3,4- b]quinoline from readily available anilines and pyrazolones was achieved. This method enables regioselective construction of the valuable heterocycles under transition-metal and oxidant-free conditions in which DMSO acts as a methine source as well as solvent making this process an environmentally benign approach. A broad range of diversely substituted aryl amines and pyrazolines are successfully employed in this reaction to access a series of pyrazolo[4,3-c]quinolones through a novel cascade mechanism. Furthermore, the application and mechanistic studies of the present methodology also demonstrated.
Applications of fluorescent sensor based on 1H-pyrazolo[3,4-b]quinoline in analytical chemistry
Mac, Marek,Uchacz, Tomasz,Danel, Andrzej,Musiolik, Hanna
, p. 1207 - 1215 (2013/11/19)
Fluorescent dye 2-[(2-Hydroxyethyl)-(1,3-diphenyl-1H-pyrazolo[3,4-b] quinolin-6-ylmethyl)-amino]ethanol (LL1) was examined for its efficiency in the detection of small inorganic cations (lithium, sodium, barium, calcium, magnesium, cadmium, lead and zinc)
Optical spectra of some 6-styrylo-1H-pyrazolo[3,4-b]quinolines
Fuks-Janczarek,Gondek,Kityk,Danel,Krzeminska,Sanetra,Kwiecien
, p. 320 - 329 (2007/10/03)
It was proposed a method of synthesis several 6-styrylo1-1H-pyrazolo[3,4-b]quinolines as promising material for optoelectronics. Particularly, 6-styryl-1,3-diphenyl-1H-pyrazolo[3,4-b]quinolines were prepared by Wadsworth-Emmons reaction. One of advantageo
1,3-Diphenyl-1H-pyrazolo[3,4-b]quinoline: A Versatile Fluorophore for the Design of Brightly Emissive Molecular Sensors
Rurack, Knut,Danel, Andrzej,Rotkiewicz, Krystyna,Grabka, Danuta,Spieles, Monika,Rettig, Wolfgang
, p. 4647 - 4650 (2007/10/03)
(Matrix Presented) The 1.3-diphenyl-1H-pyrazolo[3,4-b]-quinoline chromophore is a versatile building block for the construction of brightly fluorescent molecular sensors. Facile synthetic procedures allow integration of the chromophore into fluorophore-spacer-receptor systems as well as fluoroionophores operating via intramolecular charge transfer. Whereas the former photoinduced electron-transfer probes show strong analyte-induced fluorescence enhancement, the latter exhibit bright ratiometric dual emission. Employing prototype macrocyclic receptors, the favorable signaling features for metal ion recognition are demonstrated.