495378-93-3

Upstream product

• 76-83-5 trityl chloride 
• 23339-16-4 (2R,3S,6S)-6-ethoxy-2-(hydroxymethyl)tetrahydro-2H-pyran-3-ol 
• 55735-69-8 ethyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohexopyranoside 
• 23339-15-3 ethyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 

Downstream Products

• 1053650-96-6 Acetic acid (2R,3S,6S)-6-ethoxy-2-trityloxymethyl-tetrahydro-pyran-3-yl ester 
• 495378-94-4 ethyl 4-O-allyl-2,3-dideoxy-6-O-trityl-α-D-erythro-hexopyranoside 
• 137344-81-1 (2R,3S)-diphenylmethyl-3-<(benzyloxycarbonyl)oxy>-2-fluorotetradecanoate 
• 137432-72-5 (2R,3S)-3-<(benzyloxycarbonyl)oxy>-2-fluorotetradecanoic acid 
• 137344-80-0 (2R,3S)-diphenylmethyl-2-fluoro-3-hydroxytetradecanoate 
• 137344-78-6 (2S,3S)-methyl 3-benzyloxy-2-hydroxytetradec-6-enoate 
• 137344-79-7 (2R,3S)-methyl-3-benzyloxy-2-fluorotetradec-6-enoate 
• 137344-74-2 methyl 4-O-benzyl-2,3-dideoxy-α,β-D-erythro-hexopyranosiduronic acid 
• 137344-76-4 methyl 4-O-benzyl-2,3-dideoxy-α,β-D-erythro-hexopyranuronate 
• 64526-50-7 methyl 4-O-benzyl-2,3-dideoxy-α,β-D-erythro-hexopyranoside 
• 495379-09-4 ethyl 2,3-dideoxy-4-O-(3'R,4'S)-(3'-methylazetidin-2'-on-4'-yl)-6-O-trityl-α-D-erythro-hexopyranoside 
• 495378-95-5 ethyl 2,3-dideoxy-(Z)-4-O-propenyl-6-O-trityl-α-D-erythro-hexopyranoside 
• 495379-11-8 ethyl 2,3-dideoxy-4-O-(3'R,4'S)-(3'-methylazetidin-2'-on-4'-yl)-6-O-tosyl-α-D-erythro-hexopyranoside 
• 137344-72-0 ethyl 4-O-benzyl-6-O-triphenylmethyl-α-D-erythro-hexopyranoside 

Relevant academic research and scientific papers

Synthesis of (2R,3S)-3-[(benzyloxycarbonyl)oxy]-2-fluorotetradecanoic acid

Optically active threo-3-[(benzyloxycarbonyl)oxy]-2-fluorotetradecanoic acid, (2R,3S)-11, was synthesized from 3,4,6-tri-O-acetyl-D-glucal via methyl uronate derivative (5). Reaction of 5 with octylidene triphenylphosphorane followed by treatment with DAS