49543-90-0Relevant academic research and scientific papers
Transformation of RN=CHPh to R(R′3Si)NCH2Ph in the catalytic desulfurization of secondary thioamide with R′3SiH promoted by an iron complex
Fukumoto, Kozo,Sakai, Akane,Murai, Toshiaki,Nakazawa, Hiroshi
, p. 607 - 611 (2014)
The reaction of imine (RN=CHPh) with hydrosilane (R′3SiH) in the presence of CpFe(CO)2Me (1) revealed the formation of a hydrosilylation product (R(R′3Si)NCH2Ph). The findings helped us to understand the reaction mechanism of desulfurization of secondary thioamide catalyzed by 1 to give the corresponding imine and amine as a major and minor product, respectively.
