49583-05-3Relevant academic research and scientific papers
Gold-catalyzed C-H oxidative polyacyloxylation reaction of hindered arenes
Pradal, Alexandre,Faudot Dit Bel, Pierre,Toullec, Patrick Y.,Michelet, Veronique
, p. 2463 - 2468 (2012/09/08)
The synthesis of polyacyloxylated aromatic derivatives was achieved in moderate yields using a gold-catalyzed C-H activation strategy and di(acetoxy)iodobenzene as an oxidant. Georg Thieme Verlag Stuttgart · New York.
OXYGENATION OF AROMATIC AND ALIPHATIC HYDROCARBONS BY A NEW REAGENT SYSTEM, Fe(CH3CN)6(2+)-H2O2-Ac2O: AN EFFECTIVE MODEL REAGENT FOR MONO-OXYGENASE
Kotani, Eiichi,Kobayashi. Shigeki,Ishii, Yoko,Tobinaga, Seisho
, p. 4671 - 4679 (2007/10/02)
Reactions of aromatic and aliphatic hydrocarbons with a new system, Fe(CH3CN)6(2+) - H2O2 - Ac2O in CH3CN, gave oxygenation products with fairly high reaction efficiency ( Tables I and II )compared to known to reagent systems used as enzyme models for mono-oxygenases.Investigations of the mechanism of these reactions indicated the involvement of either complex C.FeIV(OH)(OAc)(2+), or complex D, FeIV(OAc)(2+), dependig on the organic substrate.Keywords-oxygenation; aromatic hydrocarbon; aliphatic hydrocarbon; hexakisacetonitrile iron(II) perchlorate; hydrogen peroxide; enzyme model; mono-oxygenase
