496862-08-9Relevant academic research and scientific papers
Tantalizing chemistry of the half-sandwich silylhydride complexes of niobium: Identification of likely intermediates on the way to agostic complexes
Nikonov, Georgii I.,Mountford, Philip,Dubberley, Stuart R.
, p. 258 - 260 (2008/10/08)
Reactions of the compound [NbCp(ArN)(PMe3)2] with chlorosilanes HSiRR′Cl give a series of silyl complexes [NbCp(ArN)(PMe3)(H)-(SiRR′Cl)] and [NbCp(ArN)(PMe3)(Cl)(SiRR′H)] which are likely intermediates to the agostic complexes [NbCp(ArN(RR′2Si-H...))-(PMe3)(Cl)].
