497080-01-0Relevant academic research and scientific papers
Synthesis of [2]rotaxanes by tritylative endcapping of in situ formed pseudorotaxanes having thiol or hydroxyl functionality on the axle termini
Furusho, Yoshio,Rajkumar, G.Abraham,Oku, Tomoya,Takata, Toshikazu
, p. 6609 - 6613 (2002)
Tritylative endcapping of an in situ formed pseudorotaxane consisting of dibenzo-24-crown-8 and an axle having a thiol group at the end by treatment with trityl hexafluorophosphate at room temperature gave the corresponding sulfide-type [2]rotaxane in hig
Dynamic covalent approach to [2]- and [3]rotaxanes by utilizing a reversible thiol-disulfide interchange reaction
Furusho, Yoshio,Oku, Tomoya,Hasegawa, Toshihide,Tsuboi, Akiyoshi,Kihara, Nobuhiro,Takata, Toshikazu
, p. 2895 - 2903 (2007/10/03)
A dynamic covalent approach to disulfide-containing [2]- and [3]rotaxanes is described. Symmetrical dumbbell-shaped compounds with two secondary ammonium centers and a central located disulfide bond were synthesized as components of rotaxanes. The rotaxan
