497227-90-4

Upstream product

• 208935-32-4 (4S,trans)-4,5-dihydro-4-(tert-butyldimethylsilanyloxymethyl)-2-phenyloxazoline 
• 497227-95-9 N-((1S)-2-acetoxy-1-(tert-butyldimethylsilanyloxymethyl)-3-butenyl)-benzamide 
• 482315-18-4 N-[(1S)-2-hydroxy-1-(tert-butyldimethylsilanyloxymethyl)-3-butenyl]-benzamide 
• 503560-10-9 N-[2-(tert-butyl-dimethyl-silanyloxy)-1-formyl-ethyl]-benzamide 
• 482315-14-0 (4R,5S)-2-Phenyl-5-vinyl-4,5-dihydro-oxazole-4-carboxylic acid methyl ester 
• 497227-96-0 ((4S,5S)-2-Phenyl-5-vinyl-4,5-dihydro-oxazol-4-yl)-methanol 
• 107-30-2 chloromethyl methyl ether 
• 497227-89-1 (4S,5S)-4-Hydroxymethyl-2-phenyl-5-vinyl-4,5-dihydro-oxazole-4-carboxylic acid methyl ester 

Downstream Products

• 497227-92-6 (3aS,6R,6aR)-6-((E)-3-Iodo-allyl)-3a-methoxymethoxymethyl-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one 
• 1027989-75-8 (4S,5R)-5-Formyl-4-methoxymethoxymethyl-2-phenyl-4,5-dihydro-oxazole-4-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Total synthesis of myriocin

A concise, stereocontrolled synthesis of myriocin was achieved. Key features involve diastereoselective oxazoline formation catalyzed by palladium(0), MgBr2-promoted allylic stannane addition, and palladium(0)-catalyzed coupling of a vinyl iodide with an organozinc reagent.