49809-51-0

Basic information

• Product Name: 2,3,4,5,6,7-hexahydro-1H-benzo[b][1,4]diazonine
• Synonyms: 2,3,4,5,6,7-hexahydro-1H-benzo[b][1,4]diazonine
• CAS NO: 49809-51-0
• Molecular Weight: 176.261
• Mol File: 49809-51-0.mol

Chemical Properties

• CAS DataBase Reference: 2,3,4,5,6,7-hexahydro-1H-benzo[b][1,4]diazonine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,5,6,7-hexahydro-1H-benzo[b][1,4]diazonine(49809-51-0)
• EPA Substance Registry System: 2,3,4,5,6,7-hexahydro-1H-benzo[b][1,4]diazonine(49809-51-0)

Safety Data

• Hazardous Substances Data: 49809-51-0(Hazardous Substances Data)

Upstream product

• 5622-83-3 1,2,3,4-tetrahydro-pyrido[1,2-a]benzimidazole 

Relevant articles and documents

A convenient synthesis of benzannelated diazacycloalkanes by reductive cleavage of 1,2-polymethylenebenzimidazoles

A facile procedure for the synthesis of benzannelated diazacycloalkanes 3 is elaborated on the basis of reductive cleavage of 1,2- polymethylenebenzimidazoles 2 with DIBAL-H. The reduction of the corresponding salts prepared by treatment of 1,2-polymethylenebenzimidazoles 2 with methyl iodide proceeded differently affording exclusively o-phenylenediamines 10. The limitations and scope of the method were established, and a tentative mechanism proposed.