49814-12-2Relevant academic research and scientific papers
HETEROARYLATION OF ORGANOMETALLIC DERIVATIVES OF AZOLES BY N-ACYLBENZOPYRIDINIUM SALTS
Sheinkman, A. K.,Chmilenko, T. S.,Nezdiiminoga, T. N.,Tertov, B. A.,Koshchienko, Yu. V.,Klyuev, N. A.
, p. 384 - 387 (2007/10/02)
The dimerization products 1,1'-dimethyl-2,2'-bibenzimidazolyl and 2,2'-dibenzoyl-1,1',2,2'-tetrahydro-1,1'-biisoquinoline were isolated in the reaction of 1-methyl-2-imidazolyl- and 1-methyl-2-benzimidazolylmagnesium bromides with isoquinoline (quinoline) in the presence of benzoyl chloride together with the products from the heteroarylation of benzimidazole (imidazole).Their formation indicates the possibility of reaction by the SET mechanism.
