49833-33-2

Usage

Uses

Used in Food and Beverage Industry:
Propanoic acid, 3-[(1,1-dimethylethyl)thio]-, ethyl ester is used as a flavoring agent to enhance the taste and aroma of various food and beverage products.
Used in Fragrance Industry:
Propanoic acid, 3-[(1,1-dimethylethyl)thio]-, ethyl ester is used in the production of fragrances to provide a fruity scent to various products.
Used in Various Industries as a Solvent:
Propanoic acid, 3-[(1,1-dimethylethyl)thio]-, ethyl ester is used as a solvent in various industries due to its ability to dissolve other substances and its flammable nature.

Upstream product

• 1609-40-1 3,3'-Dithiobis(propansaeure-diethylester) 
• 181820-18-8 S-(tert-butyl)trifluorothioacetate 
• 75-66-1 2-methylpropan-2-thiol 
• 140-88-5 ethyl acrylate 

Relevant academic research and scientific papers

Sulfenate substitution as a complement and alternative to sulfoxidation in the diastereoselective preparation of chiral β-substituted β-amino sulfoxides

Building from a previous communication, the reaction of sulfenate anions with chiral N-Boc-protected β-substituted β-amino iodides was evaluated as a conceptually different synthetic approach to chiral β-substituted β-amino sulfoxides. Using arenesulfenat

Remarkably mild and simple preparation of sulfenate anions from β-sulfinylesters: A new route to enantioenriched sulfoxides

(Chemical Equation Presented) A general, efficient, and experimentally simple method for the generation of sulfenate salts has been developed using β-sulfmylesters as substrates. The process is based on a retro-Michael reaction, initiated by deprotonation at low temperature. Upon treatment with alkyl halides, the liberated sulfenates are subsequently converted into sulfoxides in good to excellent yield. Extension of the methodology to an unprecedented access to nonracemic sulfoxides by introduction of an enantiopure ligand, (-)-sparteine, is also described.

Synthetic Uses of Thio- and Selenoesters of Trifluoromethylated Acids. 1. Preparation of Trifluoromethyl Sulfides and Selenides

Trifluorothioacetates (CF3CO-S-R, from (CF3CO)2O and thiols) as well as trifluoromethanethio-or trifluoromethaneselenosulfonates (CF3SO2-Y-R; Y = S, Se; from CF3SO2Na, RYYR, and Br2) can be formally decarbonylated or desulfonylated, respectively, provided that they are photolyzed at 40°C in the presence of 1 equiv of the corresponding disulfide or diselenide. Trifluoromethyl sulfides or selenides are obtained, and the added disulfide (or diselenide) is recovered after reaction. In such a way, S-(trifluoromethyl)cysteine derivatives can be obtained.