49858-45-9Relevant academic research and scientific papers
Eco-compatible three component strategies for C-S bond formation in thioether and S-aryl-carbamodithioate compounds catalyzed by copper(II) nanoparticles supported on modified AlPO4
Sharghi, Hashem,Ghaderi, Iman,Doroodmand, Mohammad Mahdi
, (2017/10/05)
One-pot and three components C-S bond formation reactions in thioethers and S-aryl-carbamodithioates have been catalyzed by a copper heterogeneous nano-catalyst supported on modified AlPO4 under different reaction conditions. The above-mentioned nano-catalyst has been characterized by various techniques such as SEM, TEM, AFM, XRD, FT-IR, UV–Vis, CV, BET, TGA, ICP and XPS spectrometry and its particle size was estimated to be between 60–110?nm. Finally, the reusability of the catalyst up to ten cycles without any significant leaching is one of the outstanding properties of the catalyst.
Fragmentation of anion radicals with elimination of aryloxy groups
Dneprovskii,Fedosov
, p. 1438 - 1443 (2007/10/03)
4-Vinylbenzyl phenyl ether, 4-phenylbenzyl phenyl ether, 1- and 2-naphthylmethyl phenyl ethers react with sodium thiophenolate under photochemical stimulation with replacement of the phenoxy group. The composition of reaction products and relation of reactivity to the structure of substrates is consistent with anion-radical mechanism. The corresponding methoxy and cyano derivatives do not undergo the reaction.
Radical-Anion Nucleophilic Substitution in Vinyl Compounds. Reaction of ω-Bromo-4-phenoxymethylstyrene with Sodium Benezenethiolate
Dneprovskii,Tuchkin
, p. 1608 - 1612 (2007/10/03)
Photoinitiated reaction of ω-bromo-4-phenoxymethylstyrene with sodium benzenethiolate results in formation of products of substitution of both the bromine atom and the phenoxy group. The product composition is well consistent with the radical-anion substi
