499992-34-6Relevant academic research and scientific papers
Diastereoselective synthesis of the pectenotoxin 2 non-anomeric AB spiroacetal
Vellucci, Danielle,Rychnovsky, Scott D.
, p. 711 - 714 (2007)
The reductive cyclization reaction of a cyanoacetal has been used to prepare the pectenotoxin 2 (PTX-2) AB spiroacetal with high diastereoselectively for the first time. The strategy is convergent and makes use of the axial-selective reductive lithiation
Approach to the tricyclic core of the tigliane-daphnane diterpenes. Concerning the utility of transannular aldol additions
Catino, Arthur J.,Sherlock, Alexandra,Shieh, Peyton,Wzorek, Joseph S.,Evans, David A.
supporting information, p. 3330 - 3333 (2013/07/26)
Two transannular (TA) aldol reactions were used to assemble the tricyclic carbon skeleton found in the tigliane and daphnane classes of diterpene natural products.
