500128-29-0Relevant academic research and scientific papers
Unexpected orthopalladation of acetophenonephenylhydrazone
Carbayo, Arancha,García-Herbosa, Gabriel,García-Granda, Santiago,Miguel, Daniel
, p. 260 - 264 (2002)
A singular hydrazonato complex of palladium has induced the unexpected orthometallation of acetophenonephenylhydrazone on the phenyl group. This is the first X-ray characterized example of an orthopalladated E-arylhydrazone of general formula ArC(R″)=N-NHAr′ where the metallated aryl is Ar′ although palladation on Ar is not hindered. Structural evidence suggests that the Pd-N(amido) bond that is present in the starting material induced the palladation of the unexpected phenyl.
