500187-77-9

Upstream product

• 74-99-7 prop-1-yne 
• 500187-73-5 C₃₁H₃₆O₁₁S₂ 
• 500187-71-3 tert-Butyl-[(2S,3R,4R,5R)-2-methoxy-4-(4-methoxy-benzyloxy)-5-vinyl-tetrahydro-furan-3-yloxy]-dimethyl-silane 
• 500187-72-4 tert-Butyl-[(2R,3R,4R,5R)-2-methoxy-4-(4-methoxy-benzyloxy)-5-vinyl-tetrahydro-furan-3-yloxy]-dimethyl-silane 
• 500187-75-7 (1R,2S,3R,4S)-3-(4-methoxybenzyloxy)-2-((tert-butyl)dimethylsilyloxy)-4-vinylcyclobutanol 
• 500187-70-2 (2S,3R,4S,5R)-2-Methoxy-4-(4-methoxy-benzyloxy)-5-vinyl-tetrahydro-furan-3-ol 
• 500187-74-6 (2R,3R,4S,5R)-2-Methoxy-4-(4-methoxy-benzyloxy)-5-vinyl-tetrahydro-furan-3-ol 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 2595-05-3 Diacetone D-glucose 
• 205934-53-8 (3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole 
• 69940-02-9 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose 
• 69940-04-1 (R)-1-[(3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 

Downstream Products

• 500187-80-4 (1R,2R,3R,4R)-3-(4-Methoxy-benzyloxy)-1-prop-1-ynyl-4-vinyl-cyclobutane-1,2-diol 

Relevant academic research and scientific papers

Zirconocene-mediated route to enantiopure 9-oxabicyclononanes functionalized on both carbon bridges

(Matrix presented) A zirconocene-mediated ring contraction of 4-vinylfuranosides generated either from D-arabinose or D-glucose is followed by sequential oxidation to the ketone and alkynyl Grignard addition. The resulting cis-cyclobutanediols are subjected in turn to thermal rearrangement and intramolecular oxymercuration-demercuration. The regiochemistry of the final ring closure is controlled by the nature of R.