500296-11-7Relevant academic research and scientific papers
A new and efficient route to homochiral γ-hydroxysulfoxides and γ-hydroxysulfones
Skarzewski, Jacek,Siedlecka, Renata,Wojaczynska, Elbieta,Zielinska-Blajet, Mariola
, p. 2105 - 2111 (2002)
Readily available (+)-(R)-1,3-diphenyl-3-phenylsulfanyl-propan-1-one 1 was oxidized to the corresponding sulfone and its reduction gave separable (1R,3R)- and (1S,3R)-1,3-diphenyl-3-phenylsulfonylpropan-1-ols. When 1 was reduced to the mixture of epimeric
Cyclization of 1,3-diaryl-3-phenylsulfanyl-1-propanols to thiochromans with the participation of [1,3]-PhS shift
Skarzewski, Jacek,Zielińska-B?ajet, Mariola,Roszak, Szczepan,Turowska-Tyrk, Ilona
, p. 3621 - 3626 (2003)
Optically active (3R,1RS)-3-aryl-1-phenyl-3-phenylsulfanyl-1-propanols were easily dehydrated forming mainly rac-cis-2-aryl-4-phenylthiochroman, and rac-cis-4-aryl-2-phenylthiochroman along with the corresponding trans-isomers. The observed reaction outco
