500707-39-1Relevant articles and documents
A concise synthesis of the tricyclic skeleton of pleuromutilin and a new approach to cycloheptenes
Bacque, Eric,Pautrat, Francois,Zard, Samir Z.
, p. 325 - 328 (2003)
(Matrix presented) A short synthesis of the tricyclic skeleton of pleuromutilin is reported, featuring an unusually efficient 8-endo-trig radical cyclization of a xanthate precursor. In the course of this study, a one-carbon ring expansion leading to cycl