501088-50-2

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 501088-37-5 4’-methyl phenyl 2-azido-2-deoxy-1-thio-β-D-glucopyranoside 
• 106-45-6 para-thiocresol 
• 501088-45-5 p-methylphenyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-thio-β-D-glucopyranoside 
• 220645-20-5 p-methylphenyl 3,4,6-tri-O-acetyl-2-deoxy-1-thio-2-(2,2,2-trichloroethyloxycarbonylamino)-β-D-glucopyranoside 

Downstream Products

• 502692-42-4 p-tolyl 2-azido-3,6-di-O-benzyl-2-deoxy-1-thio-β-D-glucopyranoside 
• 502692-43-5 (2R,3S,4R,5R,6S)-5-Amino-4-benzyloxy-2-benzyloxymethyl-6-p-tolylsulfanyl-tetrahydro-pyran-3-ol 
• 502692-44-6 p-tolyl 3,6-di-O-benzyl-2-deoxy-1-thio-2-(2,2,2-trichloroethoxy)carbamoylamino-β-D-glucopyranoside 
• 502692-45-7 Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-2-[(2R,3S,4R,5R,6S)-4-benzyloxy-2-benzyloxymethyl-6-p-tolylsulfanyl-5-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-3-yl ester 
• 501088-52-4 C₂₇H₂₅N₃O₅S 
• 1309834-96-5 C₂₇H₂₇N₃O₅S 

Relevant academic research and scientific papers

Solvent participation in a one-pot glycosylation strategy (SPOG)

Solvent participation in a one-pot glycosylation strategy (SPOG) was developed on the basis of the low concentration β-selective glycosylation method. This strategy enables the production of a β-glycosidic bond in a one-pot oligosaccharide synthesis without or with minimal use of any C-2 participating function.

Efficient formation and cleavage of benzylidene acetals by sodium hydrogen sulfate supported on silica gel

NaHSO4SiO2 was used as an efficient heterogeneous catalyst for both the formation and the cleavage of benzylidene acetals. This catalyst is compatible with many functional or protective groups. Under different solvent systems, either the formation or the cleavage of benzylidene acetals was carried out smoothly in excellent yields and with good chemoselectivity. Georg Thieme Verlag Stuttgart.

A new reactivity-based one-pot synthesis of N-acetyllactosamine oligomers

Poly-N-acetyllactosamine oligomer is a type-2 glycan core from which a number of important bioactive glycoconjugates are assembled in vivo. Development of an effective synthesis of N-acetyllactosamine oligomers will therefore provide a new chemoenzymatic