501330-43-4Relevant articles and documents
Enantioselective synthesis of butadien-2-ylcarbinols via (silylmethyl)allenic alcohols from chromium-catalyzed additions to aldehydes utilizing chiral carbazole ligands
Durán-Galván, María,Worlikar, Shilpa A.,Connell, Brian T.
scheme or table, p. 7707 - 7719 (2010/10/21)
The synthesis of chiral, nonracemic butadienylcarbinols by employing intermediate (trimethylsilyl)methylallenic alcohols is described. Allenic alcohols are obtained by treatment of aldehydes with (4-bromobut-2-ynyl) trimethylsilane in the presence of a ca
Asymmetric catalysis of Nozaki-Hiyama allylation and methallylation with a new tridentate bis(oxazolinyl)carbazole ligand
Inoue, Masahiro,Suzuki, Takahiro,Nakada, Masahisa
, p. 1140 - 1141 (2007/10/03)
This work describes the development of a new tridentate ligand effective for the asymmetric catalysis of Nozaki-Hiyama allylation and methallylation. Various aldehydes were allylated or methallylated with good enantioselectivity (86-96%), and a key interm