943786-98-9Relevant articles and documents
Enantioselective synthesis of butadien-2-ylcarbinols via (silylmethyl)allenic alcohols from chromium-catalyzed additions to aldehydes utilizing chiral carbazole ligands
Durán-Galván, María,Worlikar, Shilpa A.,Connell, Brian T.
experimental part, p. 7707 - 7719 (2010/10/21)
The synthesis of chiral, nonracemic butadienylcarbinols by employing intermediate (trimethylsilyl)methylallenic alcohols is described. Allenic alcohols are obtained by treatment of aldehydes with (4-bromobut-2-ynyl) trimethylsilane in the presence of a ca