501357-08-0Relevant academic research and scientific papers
Chemistry of diazopolycarbonyl compounds: V. Synthesis, structure, and chemical characteristics of aryl diazoacetates
Zalesov,Kataev
, p. 1666 - 1672 (2007/10/03)
Aryl diazoacetates were prepared, and basing on spectral data and quantum-chemical calculations cis-trans isomerism thereof was proved. The reactions of diazoesters with hydrochloric and sulfuric acids, triphenylphosphine, and dinitrogen tetroxide resulted respectively in aryl chloroacetates, bis(aryloxy-carbonylmethyl) sulfates, triphenylphosphoranylidenehydrazones of aryl 2-oxoethanoates, and N-oxides of diaryl 1,2,5-oxadiazole-3,4-dicarboxylates.
