502423-56-5Relevant academic research and scientific papers
Synthesis of the pentasaccharide repeating unit of the major O-antigen component from Pseudomonas syringae pv. ribicola NVPPB 1010
Bedini, Emiliano,Barone, Gaspare,Unverzagt, Carlo,Parrilli, Michelangelo
, p. 393 - 400 (2007/10/03)
The synthesis of the repeating unit of the major O-antigen component from Pseudomonas syringae pv. ribicola NVPPB 1010 is reported. The strategy used was based on the successive coupling of a trisaccharide rhamnosyl trichloroacetimidate with a rhamnosyl a
Oligomerization of a rhamnanic trisaccharide repeating unit of O-chain polysaccharides from phytopathogenic bacteria
Bedini, Emiliano,Parrilli, Michelangelo,Unverzagt, Carlo
, p. 8879 - 8882 (2007/10/03)
An efficient synthesis of a protected trisaccharide building block α-L-Rha(1→3)-α-L-Rha(1→2)-α-L-Rha related to the structure of many lipopolysaccharide O-chains from phytopathogenic bacteria has been developed. The protecting group pattern consisting of benzoyl, benzyl and chloroacetyl groups facilitated the use of the trisaccharide building block in the synthesis of two higher oligomers, an oligorhamnosyl hexasaccharide and a nonasaccharide.
