502763-90-8

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 77-76-9 2,2-dimethoxy-propane 
• 502763-89-5 4-methylphenyl 6-O-tert-butyldiphenylsilyl-1-thio-β-D-galactopyranoside 
• 28244-94-2 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside 
• 1152-39-2 p-methylphenyl-1-thio-β-D-galactopyranoside 
• 200406-58-2 4-methylphenyl 3,4-O-isopropylidene-1-thio-β-D-galactopyranoside 

Downstream Products

• 1461749-33-6 C₃₇H₄₆O₇SSi 
• 1461749-36-9 p-tolyl 2-O-levulinoyl-3,4-O-isopropylidene-1-thio-β-D-galactopyranoside 
• 1461749-38-1 p-tolyl 2-O-levulinoyl-3, 4, 6-tri-O-acetyl-1-thio-β-D-galactopyranoside 
• 1461749-39-2 p-tolyl 3, 4, 6-tri-O-acetyl-1-thio-β-D-galactopyranoside 
• 1461749-10-9 p-tolyl 2,3,4-tri-O-benzoyl-6-deoxy-β-D-galactopyranosyl-(1→2)-3,4,6-tri-O-acetyl-1-thio-β-D-galactopyranoside 
• 502692-48-0 6-[4-acetoxy-5-[5-benzyloxy-6-benzyloxymethyl-4-(4-methoxy-benzyloxy)-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-yloxy]-6-benzyloxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yloxy]-hexanoic acid methyl ester 
• 502692-49-1 6-[(2R,3R,4R,5S,6R)-4-Acetoxy-5-[(2S,3R,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-4-hydroxy-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-yloxy]-6-benzyloxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yloxy]-hexanoic acid methyl ester 
• 502692-36-6 4-Oxo-pentanoic acid (2S,3R,4S,5S,6R)-5-benzyloxy-6-benzyloxymethyl-4-(4-methoxy-benzyloxy)-2-p-tolylsulfanyl-tetrahydro-pyran-3-yl ester 
• 502763-81-7 Benzoic acid (2S,3R,4S,5S,6R)-5-benzyloxy-6-benzyloxymethyl-4-(4-methoxy-benzyloxy)-2-p-tolylsulfanyl-tetrahydro-pyran-3-yl ester 
• 502763-91-9 Benzoic acid (2S,3R,4S,5R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-p-tolylsulfanyl-tetrahydro-pyran-3-yl ester 
• 502763-80-6 Benzoic acid (2S,3R,4S,5S,6R)-5-hydroxy-6-hydroxymethyl-4-(4-methoxy-benzyloxy)-2-p-tolylsulfanyl-tetrahydro-pyran-3-yl ester 
• 220645-56-7 p-methylphenyl 2-O-benzoyl-6-O-tert-butyldiphenylsilyl-3-O-p-methoxybenzyl-1-thio-β-D-galactopyranoside 
• 502763-79-3 benzoic acid 4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-6-p-tolylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester 

Relevant academic research and scientific papers

Unexpected cyclization during the mitsunobu reaction of d -talose derivatives

A d-talose derivative underwent unexpected cyclization during a Mitsunobu reaction. A plausible pathway for the reaction involves an attack of the nucleophilic azide on the benzyl ring by intramolecular cyclization with loss of the benzyl group. These newly formed, unexpected compounds may be used in the synthesis of derivatives of C-nucleosides. Georg Thieme Verlag Stuttgart · New York.

Synthesis of the pentasaccharide moiety of thornasterside A

The synthesis of the pentasaccharide moiety of thornasteroside A, the first asterosaponin isolated from starfish in 1978 has been achieved for the first time. Initially, a [3+2] convergent strategy was attempted, but the β(1→4) glycosidic linkage between

Reactivity-based one-pot synthesis of a Lewis Y carbohydrate hapten: A colon-rectal cancer antigen determinant

The stereospecific synthesis of a tumor-related carbohydrate antigenic hapten, Lewis Y, from three basic building units 1 - 3 has been achieved by a reactivity-based one-pot strategy. RRV = relative reactivity value.