502966-76-9Relevant academic research and scientific papers
Formation of novel phosphide dichloride Zr complex from trichloride Zr complex with a secondary phosphine-pendant cyclopentadienyl ligand: Structure of [{η5-C5H4(CH2) 2PMes-κP}ZrCL2(N-methylimidazole)2] (Mes = 2,4,6-trimethylphenyl)
Ishiyama, Takeshi,Mizuta, Tsutomu,Miyoshi, Katsuhiko,Nakazawa, Hiroshi
, p. 70 - 71 (2003)
The reaction of [{η5-C5H4(CH2) 2P(H)Mes-κP}ZrCl3(tht)] (1; Mes = 2,4,6-trimethylphenyl; tht = tetrahydrothiophene) with 1 equiv of NaCPh3, followed by treatment with N-methylimidazole gave a novel phosphide-pendant dichloride complex [{η5-C5H4(CH2) 2PMes-κP}ZrCl2(N-methylimidazole)2] (4) with liberation of HCPh3. The product (4) is the first dichloride terminal phosphide Zr complex characterized by X-ray crystallographic analysis.
