503000-26-8

Upstream product

• 503000-40-6 C₂₇H₃₆SiO₂C₂H₄SiC₃H₈ 
• 503000-50-8 6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-6-vinyl-octa-2,7-dienoic acid ethyl ester 
• 503000-51-9 tert-Butyl-{4-[2-((2S,3R)-3-iodomethyl-oxiranyl)-ethyl]-4-vinyl-hex-5-enyloxy}-diphenyl-silane 
• 503000-47-3 1-[3-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-6-(tert-butyl-diphenyl-silanyloxy)-3-vinyl-hexylselanyl]-2-nitro-benzene 
• 1138157-67-1 C₃₃H₅₀O₂Si₂ 
• 91266-03-4 tert-butyl-pent-4-ynyloxy-diphenyl-silane 
• 1138157-65-9 C₃₃H₅₁IO₂Si₂ 
• 1138157-62-6 C₃₀H₄₄O₂Si₂ 
• 1138157-60-4 C₃₀H₄₂O₂Si₂ 
• 1265214-87-6 C₂₅H₃₄O₂Si 
• 1122478-50-5 6-(tert-butyldiphenylsilanyloxy)-3-methylene-hexan-2-ol 
• 503000-31-5 3-[3-(tert-butyldimethylsilyloxy)propyl]-3-[3-(tert-butyldiphenylsilyloxy)propyl]pent-4-en-1-ol 
• 503000-29-1 ethyl 3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enoate 
• 503000-30-4 3-[3-(tert-butyldimethylsiloxy)propyl]-6-(tert-butyldiphenylsiloxy)hex-2-enyl Vinyl Ether 

Downstream Products

• 503000-34-8 3-((S)-4-Oxo-1-vinyl-cyclohex-2-enyl)-propionic acid 
• 503000-35-9 (4S)-4-(2-carbamoylethyl)-4-vinyl-2-cyclohexene-1-one 
• 4724-62-3 (3¹S,6aR,9aR)-6a-ethyloctahydro-1H-pyrrolo[3,2,1-ij]quinolin-9(2H)-one 
• 503000-55-3 C₁₁H₁₅O₂NH₂C₂H₆ 
• 503000-58-6 N-(6a-ethyl-decahydro-pyrrolo[3,2,1-ij]quinolin-9-ylidene)-N'-(2-methoxy-phenyl)-hydrazine 
• 503000-53-1 (1S,4R)-4-(3-Hydroxy-propyl)-4-vinyl-cyclohex-2-enol 

Relevant academic research and scientific papers

Diastereoselective construction of chiral building blocks for the synthesis of indole alkaloids using an intramolecular Heck reaction

Highly diastereoselective construction of the chiral building blocks, with an allylic quaternary carbon stereogenic center, for the synthesis of indole alkaloids has been accomplished by employing a 1,4-chirality transfer via the intramolecular Heck react

Total synthesis of (-)-aspidospermine via diastereoselective ring-closing olefin metathesis

(Matrix presented) An enantiocontrolled total synthesis of (-)-aspidospermine has been achieved. The key element of the strategy is the diastereoselective construction of the quaternary stereogenic center employing 1,4-asymmetric induction during the ring-closing olefin metathesis.