503000-55-3Relevant articles and documents
Total synthesis of (-)-aspidospermine via diastereoselective ring-closing olefin metathesis
Fukuda, Yu-Ichi,Shindo, Mitsuru,Shishido, Kozo
, p. 749 - 751 (2003)
(Matrix presented) An enantiocontrolled total synthesis of (-)-aspidospermine has been achieved. The key element of the strategy is the diastereoselective construction of the quaternary stereogenic center employing 1,4-asymmetric induction during the ring-closing olefin metathesis.