503071-46-3

Basic information

• Product Name: Silane, bis(1-methylethyl)(phenylmethoxy)-
• Synonyms: benzyloxydiisopropylsilane
• CAS NO: 503071-46-3
• Molecular Formula: C13H22OSi
• Molecular Weight: 222.403
• Mol File: 503071-46-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, bis(1-methylethyl)(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, bis(1-methylethyl)(phenylmethoxy)-(503071-46-3)
• EPA Substance Registry System: Silane, bis(1-methylethyl)(phenylmethoxy)-(503071-46-3)

Safety Data

• Hazardous Substances Data: 503071-46-3(Hazardous Substances Data)

Upstream product

• 2227-29-4 chlorodiisopropylsilane 
• 100-51-6 benzyl alcohol 
• 93-58-3 benzoic acid methyl ester 
• 18209-66-0 di-isopropylsilane 

Downstream Products

• 145691-66-3 Ethyl 3-(2-ethoxycarbonylethenyl)-5-hydroxymethylcinnamate 
• 937-54-2 benzyl isopropyl ether 
• 92411-30-8 2,2,4,4,6,6-hexaisopropylcyclotrisiloxane 
• 103-50-4 dibenzyl ether 

Relevant articles and documents

Pincer Ruthenium Catalyzed Intramolecular Silylation of C(sp 2)-H Bonds

Reported herein is a highly efficient intramolecular silylation of aromatic C-H bonds catalyzed by a pincer ruthenium complex, giving benzoxasiloles under relatively mild reaction conditions with broad substrate scope and low catalyst loadings. The silylation product can be further converted into a biaryl product by Pd-catalyzed HiyamaDenmark cross-coupling reactions.

Meta-selective C-H functionalization using a nitrile-based directing group and cleavable Si-tether

A nitrile-based template that enables meta-selective C-H bond functionalization was developed. The template is applicable to a range of substituted arenes and tolerates a variety of functional groups. The directing group uses a silicon atom for attachment