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Benzyl ether
Cas No: 103-50-4
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Benzyl ether Manufacturer/High quality/Best price/In stock
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USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Dibenzyl Ether with high purity
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Benzyl ether
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Amadis Chemical offer CAS#103-50-4;CAT#A800755
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Dibenzyl ether
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Benzyl ether
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Pharmaceutical Grade CAS 103-50-4 with competitive price
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USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
Benzyl ether 103-50-4
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103-50-4 Usage

Chemical Properties

colourless liquid

Definition

ChEBI: A benzyl ether in which the oxygen atom is connected to two benzyl groups.

Purification Methods

Reflux the ether over sodium, then distil it under reduced pressure. It been purified by fractional freezing. [Beilstein 6 IV 2240.]

General Description

Colorless liquid with a mild odor.

Health Hazard

Inhalation may cause nausea because of disagreeable odor. Contact of liquid with eyes causes mild irritation. Prolonged exposure of skin to liquid causes reddening and irritation. Ingestion produces nausea.

Reactivity Profile

Benzyl ether can act as a base to form salts with strong acids and addition complexes with Lewis acids. May react violently with strong oxidizing agents. Burns readily but relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond.

Air & Water Reactions

Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. Insoluble in water.

Fire Hazard

Benzyl ether is combustible.

Uses

Plasticizer for nitrocellulose; solvent in perfumery.

103-50-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (Y0001628)  Tribenoside impurity D  European Pharmacopoeia (EP) Reference Standard 103-50-4 Y0001628 1,880.19CNY Detail
Sigma-Aldrich (49673)  Dibenzylether  analytical standard 103-50-4 49673-5ML 1,817.01CNY Detail
Sigma-Aldrich (49673)  Dibenzylether  analytical standard 103-50-4 49673-1ML 458.64CNY Detail
Alfa Aesar (A18447)  Dibenzyl ether, 98+%    103-50-4 2500g 774.0CNY Detail
Alfa Aesar (A18447)  Dibenzyl ether, 98+%    103-50-4 500g 217.0CNY Detail
Alfa Aesar (A18447)  Dibenzyl ether, 98+%    103-50-4 250g 211.0CNY Detail

103-50-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name dibenzyl ether

1.2 Other means of identification

Product number -
Other names phenylmethoxymethylbenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:103-50-4 SDS

103-50-4Synthetic route

benzyl alcohol
100-51-6

benzyl alcohol

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With copper(ll) bromide at 175℃; for 8h; Reagent/catalyst;100%
With (NH4)2.8H0.9[ε-VMo9.4V2.6O40Bi2]·7.2H2O at 129.84℃; for 3h; Catalytic behavior; Reagent/catalyst;97%
With benzyl bromide In neat (no solvent) at 120℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Sealed tube; Green chemistry;97%
benzaldehyde
100-52-7

benzaldehyde

benzyl alcohol
100-51-6

benzyl alcohol

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With triethylsilane; chloro-trimethyl-silane In dichloromethane at 20℃; for 3h;100%
With triethylsilane; ytterbium(III) triflate In 1,2-dichloro-ethane for 4h; Reflux;99%
With phenyltellurotrimethylsilane; zinc(II) iodide In benzene for 3h; Ambient temperature;96%
benzyl bromide
100-39-0

benzyl bromide

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With sodium hydride; N,N-dimethyl-formamide at 20℃; for 24h;99%
With 18-crown-6 ether; cesium fluoride; bis(tri-n-butyltin)oxide In acetonitrile at 55℃; for 8h;71%
With aluminum oxide In neat (no solvent) at 25℃; for 25h;39%
benzaldehyde
100-52-7

benzaldehyde

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With triethylsilane; trifluorormethanesulfonic acid In nitromethane at 20℃; for 0.0166667h;99%
With triethylsilane; silver tetrafluoroborate at 20℃; for 0.0833333h; Catalytic behavior; Reagent/catalyst; Temperature; Green chemistry;98%
With 1,1,3,3-Tetramethyldisiloxane; trimethylsilyl trifluoromethanesulfonate In benzene for 0.333333h; Heating;97%
1-(5-methylfuran-2-yl)pentan-1-ol
70396-63-3, 14313-18-9

1-(5-methylfuran-2-yl)pentan-1-ol

benzyl alcohol
100-51-6

benzyl alcohol

A

dibenzyl ether
103-50-4

dibenzyl ether

B

2-(1-Benzyloxy-pentyl)-5-methyl-furan

2-(1-Benzyloxy-pentyl)-5-methyl-furan

Conditions
ConditionsYield
With magnesium(II) perchlorate In diethyl ether for 1h; Ambient temperature;A n/a
B 99%
triethylsilane
617-86-7

triethylsilane

benzaldehyde
100-52-7

benzaldehyde

A

hexaethyl disiloxane
994-49-0

hexaethyl disiloxane

B

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With uranyl(VI) triflate In dichloromethane at 20℃; for 1h; Reagent/catalyst; Solvent; Temperature;A n/a
B 99%
With aluminium(III) triflate at 20℃; Inert atmosphere; Sonication; neat (no solvent);A n/a
B 100 %Chromat.
Dimethylphenylsilane
766-77-8

Dimethylphenylsilane

benzaldehyde
100-52-7

benzaldehyde

A

dibenzyl ether
103-50-4

dibenzyl ether

B

1,1,3,3-tetramethyl-1,3-diphenyldisiloxane
56-33-7

1,1,3,3-tetramethyl-1,3-diphenyldisiloxane

Conditions
ConditionsYield
With uranyl(VI) triflate In dichloromethane at 20℃; for 1h;A 99%
B n/a
benzaldehyde
100-52-7

benzaldehyde

HSiPh3
789-25-3

HSiPh3

A

hexaphenyldisiloxanne
1829-40-9

hexaphenyldisiloxanne

B

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With uranyl(VI) triflate In dichloromethane at 20℃; for 6h;A n/a
B 99%
benzyloxy-trimethylsilane
14642-79-6

benzyloxy-trimethylsilane

benzaldehyde
100-52-7

benzaldehyde

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With triethylsilane; iron(III) chloride In nitromethane at 20℃; for 0.166667h;98%
With triethylsilane; trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - -30℃;96%
With triethylsilane; bismuth(III) bromide In acetonitrile for 0.0833333h; Ambient temperature;84%
With triethylsilane; triphenylmethyl perchlorate In dichloromethane at 0℃;72%
1-((benzyloxy)methyl)-4-iodobenzene
1228384-40-4

1-((benzyloxy)methyl)-4-iodobenzene

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With potassium tert-butylate; benzyl alcohol In N,N-dimethyl-formamide at 90℃; for 2h; Schlenk technique; Inert atmosphere;97%
benzyl bromide
100-39-0

benzyl bromide

A

dibenzyl ether
103-50-4

dibenzyl ether

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With potassium tert-butylate; trifluoroacetic acid In tetrahydrofuran; dichloromethane; waterA 96%
B n/a
benzyl bromide
100-39-0

benzyl bromide

(±)-4-hydroxymethyl-4-vinyl-dihydro-furan-2-one
172843-34-4

(±)-4-hydroxymethyl-4-vinyl-dihydro-furan-2-one

A

dibenzyl ether
103-50-4

dibenzyl ether

B

4-<(benzyloxy)methyl>-4-<(tert-butyldimethylsiloxy)methyl>tetrahydro-2-furanone
130838-67-4

4-<(benzyloxy)methyl>-4-<(tert-butyldimethylsiloxy)methyl>tetrahydro-2-furanone

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In tetrahydrofuran; ethyl acetate; mineral oilA n/a
B 96%
2-(benzyloxy)-5-fluoroaniline
937596-55-9

2-(benzyloxy)-5-fluoroaniline

A

N-Acetyl-2-benzyloxy-4-fluoroaniline
159471-66-6

N-Acetyl-2-benzyloxy-4-fluoroaniline

B

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With acetic anhydride In pyridine; (2S)-N-methyl-1-phenylpropan-2-amine hydrateA 96%
B n/a
ethyl acetoacetate
141-97-9

ethyl acetoacetate

benzyl alcohol
100-51-6

benzyl alcohol

A

dibenzyl ether
103-50-4

dibenzyl ether

B

Ethyl 2-benzylacetoacetate
620-79-1

Ethyl 2-benzylacetoacetate

Conditions
ConditionsYield
With 12-tungestocobaltic acid supported on nano silica at 80℃; for 0.05h; neat (no solvent);A n/a
B 95%
methanol
67-56-1

methanol

benzyl alcohol
100-51-6

benzyl alcohol

A

benzyl methyl ether
538-86-3

benzyl methyl ether

B

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With copper(ll) bromide at 175℃; for 10h; Inert atmosphere; Sealed tube;A 93%
B 7%
With phosphoric acid at 350℃; under 36775.4 Torr;
With Cp*Ir(Cl)2(nBu2Im); silver trifluoromethanesulfonate at 110℃; for 12h;A 88 %Spectr.
B 6 %Spectr.
2-benzyloxy-1-methylpyridinium triflate

2-benzyloxy-1-methylpyridinium triflate

2-(2-methoxyethoxy)ethyl alcohol
111-77-3

2-(2-methoxyethoxy)ethyl alcohol

A

1-methyl-2-pyridone
694-85-9

1-methyl-2-pyridone

B

dibenzyl ether
103-50-4

dibenzyl ether

C

diethylene glycol benzyl methyl diether

diethylene glycol benzyl methyl diether

Conditions
ConditionsYield
With α,α,α-trifluorotoluene; magnesium oxide at 83℃; for 24h;A n/a
B n/a
C 93%
6-carboxy-7,8-dihydroxy-3-trifluoroacetyl-1-phenyl-2,3,4,5-tetrahydro-1H-3-benzazepine

6-carboxy-7,8-dihydroxy-3-trifluoroacetyl-1-phenyl-2,3,4,5-tetrahydro-1H-3-benzazepine

benzyl chloride
100-44-7

benzyl chloride

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With potassium carbonate In N-methyl-acetamide93%
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

benzyl alcohol
100-51-6

benzyl alcohol

A

dilauryl ether
4542-57-8

dilauryl ether

B

dibenzyl ether
103-50-4

dibenzyl ether

C

((dodecyloxy)methyl)benzene
39695-18-6

((dodecyloxy)methyl)benzene

Conditions
ConditionsYield
With Cp*Ir(Cl)2(nBu2Im); silver trifluoromethanesulfonate at 130℃; for 3h;A n/a
B 2 %Spectr.
C 93%
methyl (2RS,3RS)-3-hydroxy-2-tetradecyloctadecanoate
17369-87-8, 18951-36-5, 23053-16-9, 81872-27-7, 87333-63-9, 118204-68-5

methyl (2RS,3RS)-3-hydroxy-2-tetradecyloctadecanoate

O-benzyl 2,2,2-trichloroacetimidate
81927-55-1

O-benzyl 2,2,2-trichloroacetimidate

A

dibenzyl ether
103-50-4

dibenzyl ether

methyl (2RS,3RS)-3-benzyloxy-2-tetradecyloctadecanoate

methyl (2RS,3RS)-3-benzyloxy-2-tetradecyloctadecanoate

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In dichloromethane; cyclohexaneA n/a
B 92%
potassium α-benzyloxymethyltrifluoroborate

potassium α-benzyloxymethyltrifluoroborate

phenyl methanesulfonate
16156-59-5

phenyl methanesulfonate

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With potassium phosphate; 1,1'-bis(diisopropylphosphino)ferrocene; (2'-amino-[1,1'-biphenyl]-2-yl)palladium(II)chloride dimer In water; tert-butyl alcohol at 110℃; for 20h; Suzuki-Miyaura cross coupling; Inert atmosphere;92%
benzyl alcohol
100-51-6

benzyl alcohol

A

Benzyl acetate
140-11-4

Benzyl acetate

B

dibenzyl ether
103-50-4

dibenzyl ether

C

methyl 3-O-benzyl-4,6-O-benzylidene-β-D-idopyranoside
1385089-67-7

methyl 3-O-benzyl-4,6-O-benzylidene-β-D-idopyranoside

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane for 72h; regioselective reaction;A n/a
B 92%
C 64%
benzoic acid
65-85-0

benzoic acid

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With 1,1,3,3-Tetramethyldisiloxane; copper(II) bis(trifluoromethanesulfonate) In methyl cyclohexane at 100℃; for 16h; sealed tube;91%
With sulfuric acid bei der elektrolytischen Reduktion;
acetylacetone
123-54-6

acetylacetone

benzyl alcohol
100-51-6

benzyl alcohol

A

3-benzyl-pentane-2,4-dione
1134-87-8

3-benzyl-pentane-2,4-dione

B

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With 12-tungestocobaltic acid supported on nano silica at 80℃; for 0.0333333h; neat (no solvent);A 91%
B n/a
With Al3+-exchanged montmorillonite In nitromethane at 100℃; for 0.5h; Product distribution; Further Variations:; Solvents; Reagents;A 83 % Chromat.
B 12 % Chromat.
propan-1-ol
71-23-8

propan-1-ol

benzyl alcohol
100-51-6

benzyl alcohol

A

dibenzyl ether
103-50-4

dibenzyl ether

B

benzyl propyl ether
937-61-1

benzyl propyl ether

Conditions
ConditionsYield
With copper(ll) bromide at 175℃; for 10h; Inert atmosphere; Sealed tube;A 9%
B 91%
benzyl alcohol
100-51-6

benzyl alcohol

butan-1-ol
71-36-3

butan-1-ol

A

dibenzyl ether
103-50-4

dibenzyl ether

B

benzyl 1-butyl ether
588-67-0

benzyl 1-butyl ether

Conditions
ConditionsYield
With copper(ll) bromide at 175℃; for 10h; Temperature; Time; Reagent/catalyst; Inert atmosphere; Sealed tube;A 8%
B 91%
benzyl chloride
100-44-7

benzyl chloride

benzyl alcohol
100-51-6

benzyl alcohol

dibenzyl ether
103-50-4

dibenzyl ether

Conditions
ConditionsYield
With iron(III) perchlorate at 100℃; for 1h; neat (no solvent);90%
copper acetylacetonate for 5h; Heating;60%
at 25 - 45℃; Kinetics; Mechanism; Thermodynamic data; solvolysis in other alcohols; var. conc. and temp.; rate constants; ΔH, ΔS;
ethanol
64-17-5

ethanol

benzyl alcohol
100-51-6

benzyl alcohol

A

dibenzyl ether
103-50-4

dibenzyl ether

B

1-(ethoxymethyl)benzene
539-30-0

1-(ethoxymethyl)benzene

Conditions
ConditionsYield
With copper(ll) bromide at 175℃; for 10h; Inert atmosphere; Sealed tube;A 10%
B 90%
With sulfuric acid
benzaldehyde
100-52-7

benzaldehyde

(benzyloxy)diisopropylsilane
503071-46-3

(benzyloxy)diisopropylsilane

A

dibenzyl ether
103-50-4

dibenzyl ether

B

2,2,4,4,6,6-hexaisopropylcyclotrisiloxane
92411-30-8

2,2,4,4,6,6-hexaisopropylcyclotrisiloxane

Conditions
ConditionsYield
bismuth(III) bromide; chlorodiisopropylsilane In acetonitrileA 90%
B n/a
benzyl alcohol
100-51-6

benzyl alcohol

A

dibenzyl ether
103-50-4

dibenzyl ether

B

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With polystyrene-supported(catecholato) oxoRe cat. act. by iPrOH; dimethyl sulfoxide In toluene for 2h; Heating; Dean-Stark apparatus;A n/a
B 90%
With Cp*Ir(Cl)2(nBu2Im); silver trifluoromethanesulfonate at 130℃; for 12h;A 10 %Spectr.
B 80 %Spectr.
With ruthenium trichloride; 1,3-bis-(diphenylphosphino)propane; nitrobenzene at 150℃; for 16h; Inert atmosphere;
4-benzyloxy-N,N-bis(2-(tert-butyldimethylsilyloxy)ethyl)aniline
444667-48-5

4-benzyloxy-N,N-bis(2-(tert-butyldimethylsilyloxy)ethyl)aniline

dibenzyl ether
103-50-4

dibenzyl ether

4-[N,N-bis(2-(tert-butyldimethylsilyloxy)ethyl)amino]phenol
444667-49-6

4-[N,N-bis(2-(tert-butyldimethylsilyloxy)ethyl)amino]phenol

Conditions
ConditionsYield
palladium-carbon In tetrahydrofuran100%
dibenzyl ether
103-50-4

dibenzyl ether

benzoyl chloride
98-88-4

benzoyl chloride

benzoic acid benzyl ester
120-51-4

benzoic acid benzyl ester

Conditions
ConditionsYield
With zinc(II) oxide In neat (no solvent) at 0 - 20℃; for 2.5h; Green chemistry;98%
dibenzyl ether
103-50-4

dibenzyl ether

acetic anhydride
108-24-7

acetic anhydride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With aminosulfonic acid In acetic acid at 60℃; for 4h;96%
FeCl3-Montmorillonite K-10 at 70℃; for 22h;94%
sulfuric acid In water at 140℃; for 3h; Conversion of starting material;79%
Acetyl bromide
506-96-7

Acetyl bromide

dibenzyl ether
103-50-4

dibenzyl ether

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With lithium bromide In dichloromethane at 30 - 35℃; for 6h; Inert atmosphere;96%
dibenzyl ether
103-50-4

dibenzyl ether

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With ferric nitrate at 60℃; for 0.25h;95%
With nitric acid In dichloromethane at 20℃; for 1h;92%
With water; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate In acetonitrile at 20℃; for 8h;86%
dibenzyl ether
103-50-4

dibenzyl ether

3-O-benzyl-1,2-O-isopropylidene-α-D-allofuranose
57099-04-4

3-O-benzyl-1,2-O-isopropylidene-α-D-allofuranose

Conditions
ConditionsYield
In acetic acid94%
dibenzyl ether
103-50-4

dibenzyl ether

1-phenylcyanamide
622-34-4

1-phenylcyanamide

N-phenyl-N'-benzylurea
1467-21-6

N-phenyl-N'-benzylurea

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In acetic acid at 40 - 50℃; for 2h; Reagent/catalyst; Solvent; Time; Ritter Amidation;94%

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