503073-34-5

Upstream product

• 75-36-5 acetyl chloride 
• 360574-95-4 2-[hydroxy-(3-nitro-phenyl)-methyl]-acrylic acid methyl ester 
• 99-61-6 3-nitro-benzaldehyde 
• 108-24-7 acetic anhydride 

Downstream Products

• 853195-00-3 (E)-2-Aminomethyl-3-(3-nitro-phenyl)-acrylic acid methyl ester 
• 1000697-52-8 3-(3-nitrobenzyl)-7,8-dihydro-6H-chromene-2,5-dione 
• 1000697-54-0 3-(3-nitrobenzyl)-7,7-dimethyl-7,8-dihydro-6H-chromene-2,5-dione 
• 1189520-20-4 (E)-5-(3-nitrobenzylidene)-2-(3-methoxyphenyl)-5,6-dihydropyrimidin-4(3H)-one 
• 1173927-25-7 6-(3-nitrobenzyl)-5H-thiazolo[3,2-a]pyrimidin-5-one 
• 594835-20-8 methyl (2Z)-2-{[(4-methylphenyl)sulfonyl]methyl}-3-(3-nitrophenyl)prop-2-enoate 
• 1417543-81-7 (4E)-4-[(2-nitrophenyl)methylidene]-5-oxopyrazolidine-1-carboximidamide 
• 1417543-87-3 4-[(3-nitrophenyl)methyl]-5-oxo-2,5-dihydro-1H-pyrazole-1-carboximidamide 

Relevant academic research and scientific papers

N-bromosuccinimide-mediated radical cyclization of 3-arylallyl azides: Synthesis of 3-substituted quinolines

Visible light irradiation of N-bromosuccinimide serves as an effective means to convert methyl 2-(azidomethyl)-3-arylpropenoates and 2-(azidomethyl)-3-arylacrylonitriles to the corresponding iminyl radicals via ?±-hydrogen abstraction and subsequent extrusion of dinitrogen. Thus formed iminyl radicals then undergo intramolecular ortho attack on the aryl ring, affording methyl quin-oline-3-carboxylates and quinoline-3-carbonitriles respectively.

Synthesis, characterization and antimicrobial activity of some new Baylis-Hillman derived benzothiazolo pyrimidinone derivatives

A series of Baylis-Hillman derived 22 new benzothiazolo pyrimidinone derivatives have been synthesized from Baylis-Hillman acetates and 2-amino benzothiazole under neat conditions with high yields. All the newly synthesized compounds have been characteriz

Heterocycles from Morita-Baylis-Hillman adducts: Synthesis of 5-oxopyrazolidines, arylidene-5-oxopyrazolidines, and oxo-2,5-dihydro-pyrazols

Starting from Morita-Baylis-Hillman (MBH) adducts, an approach for the synthesis of oxopyrazolidines, arylidene-oxopyrazolidines, and oxo-2,5-dihydropyrazoles is described. The method is based on a tandem process involving a Michael addition of amino-guan

Synthesis of allyl aryl sulfone derivatives from Baylis-Hillman acetates in water

Various phenyl and p-tolyl allyl sulfone derivatives were prepared stereoselectively by reacting Baylis-Hillman acetates with sodium 4-R-benzenesulfinate (R=H, Me) in H2O. The reaction was very efficient in providing the corresponding sulfone d

The Baylis-Hillman chemistry in aqueous media: Elucidation of mechanism for synthesis of ether side-product leads to an efficient approach to C-O bond formation

The formation of an ether from the Baylis-Hillman (BH) adduct during the BH reaction of 5-isoxazolecarboxaldehydes is a common phenomenon if the reaction is allowed to proceed for longer periods. The amount of formation of such ethers depends on the acryl