5032-65-5

Basic information

• Product Name: Propanenitrile, 3-(diphenylphosphino)-
• CAS NO: 5032-65-5
• Molecular Formula: C15H14NP
• Molecular Weight: 239.257
• Mol File: 5032-65-5.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: Propanenitrile, 3-(diphenylphosphino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanenitrile, 3-(diphenylphosphino)-(5032-65-5)
• EPA Substance Registry System: Propanenitrile, 3-(diphenylphosphino)-(5032-65-5)

Safety Data

• Hazardous Substances Data: 5032-65-5(Hazardous Substances Data)

Upstream product

• 107-13-1 acrylonitrile 
• 829-85-6 diphenylphosphane 
• 4559-70-0 Diphenylphosphine oxide 
• 678187-53-6 (tert-butyldimethylsilyl)diphenylphosphine 
• 5032-67-7 3-(diphenylphosphinyl)propanenitrile 
• 2417-90-5 bromopropionitrile 

Downstream Products

• 2848-01-3 3-(diphenylphosphino)propionic acid 
• 16605-03-1 (3-aminopropyl)diphenylphosphine 
• 5032-67-7 3-(diphenylphosphinyl)propanenitrile 
• 1413935-74-6 trans-[Co(N,N-dimethyldithiocarbamate)2{P(CH₂CH₂CN)Ph₂}2]BF₄ 
• 137197-60-5 {rhodium(I) (carbonyl)(2-cyanoethyldiphenylphosphine)2 (nitrato)} 
• 137197-59-2 {rhodium(III) (carbonyl)(2-cyanoethyldiphenylphosphine)2 (chloro)3} 
• 137197-62-7 {rhodium(I) (carbonyl)(2-cyanoethyldiphenylphosphine)2 (pyridine)}nitrate 

Relevant articles and documents

Rhodium Complexes in P-C Bond Formation: Key Role of a Hydrido Ligand

Olefin hydrophosphanation is an attractive route for the atom-economical synthesis of functionalized phosphanes. This reaction involves the formation of P-C and H-C bonds. Thus, complexes that contain both hydrido and phosphanido functionalities are of gr

A bench-stable copper photocatalyst for the rapid hydrophosphination of activated and unactivated alkenes

Cu(acac)2 (1) is a highly active catalyst for the hydrophosphination of alkenes. Photocatalytic conditions are critical, and provide high conversions with unactivated substrates that have never before been reported with an air-stable catalyst or at ambient temperature. The commercial availability, ease of use, and broad substrate scope of compound 1 make hydrophosphination more available to synthetic chemists.

Palladium nanocatalysts in glycerol: Tuning the reactivity by effect of the stabilizer

Palladium nanoparticles (PdNPs) prepared in neat glycerol containing TPPTS (tris(3-sulfophenyl)phosphine trisodium salt) or cinchona-based alkaloids (cinchonidine, quinidine) as capping agents, were applied as catalysts in fluoride-free Hiyama couplings and conjugate additions with the aim of evaluating the influence of the stabilizer in the catalytic reactivity. Therefore, PdNPs stabilized by phosphine favored C–C cross-couplings, whereas those containing alkaloids showed enhanced suitability for C–C homo-couplings and conjugate additions. The metal/stabilizer coordination mode, i.e. Pd–P dative bond and π-π interaction between quinoline moiety and palladium surface, is certainly key for the stabilization of different active metallic species and then promoting distinctive catalytic pathways.