503445-45-2Relevant academic research and scientific papers
Synthesis and reactivity of cyclopentadienyl and indenyl ligands bearing ω-fluorinated pendant groups. Crystal structure of (ortho-F-C6H4)-CPh2-C5H 4SiMe3
Khvorost,Lemenovskii,Ustynyuk,Rufanov,Kipke
, p. 1207 - 1214 (2007/10/03)
A series of cyclopentadienes and indenes with ω-fluorinated pendant groups have been synthesised and their reactivity towards metallating agents n-BuLi, NaH, TIOEt, Me3SiCl, Me3SnCl, TiHal4, ZrX4 (X = Cl, NMe2) has been investigated. The crystal structure of 1-trimethylsilyl-3-(diphenyl-ortho-fluorophenyl-methyl)-cyclopentadiene (3) was determined.
